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Posts Tagged ‘syngas’

Microbial Catalytic Conversion of Syngas to Ethanol

May 21st, 2011

Gasification is a process by which lignocellulosic substrates are partially oxidized under high temperatures to liberate syngas which can readily be converted to ethanol by either inorganic or biocatalytic conversions. Biological production of fuel from syngas offers several advantages over catalytic techniques including conversion occurring under mild temperatures and pressures than catalytic reactors, higher reaction specificity of enzymes, reduced costs and no stoichiometric limitations.

The process includes pumping of the gas mixture into the bioreactor where microbes under anaerobic condition will catalytically reduce the oxides of carbon into hydrides as ethanol and subsequently resolved form the reactor mix by distillation and repeated as cycles. Several acetogenic microbes are capable of metabolizing syngas into ethanol. Two of the most promising strains are Butyribacterium methylotrophicum and Clostridium ljungdahlii. Eventhough advantages have been pointed, constraints including contamination, strain performance, technical optimization for the sustained maintenance of pure, viable microbial cultures and stable anaerobic incubation to avoid lethal oxygenation toxicity to producer organisms.

 

Gasification Suppliers – Pyrolysis, Syngas, Small-scale Gasifiers

July 12th, 2009

A long and excellent list of providers and suppliers of gasification systems provided here.

From Bioenergylists site

On the Prospects of Butanol from Syngas

May 25th, 2009

Here’s a nice post on butanol and specifically on the prospects of making butanol using the gasification-syngas-catalytic synthesis route.

To put it rather simply, the author doesn’t think it is worth trying to make butanol using the gasification route. Why?

“The challenge is that syngas (produced from gasification) doesn’t like to form butanol. You can form a little bit directly, but CO (carbon monoxide) likes to do lots of things besides form a C4 alcohol like butanol.

Methanol is not a problem. You can also produce ethanol, which is what Range Fuels is planning on doing (although you almost always have methanol to deal with as well). But the selectivity falls off sharply as you go to higher alcohols. By the time you get to butanol, you are lucky if 5% of the product is butanol. More typical is 1-2%.” (an NREL post is also provided as reference by author)

Let’s get this straight. The author isn’t saying butanol is a bad biofuel, in fact he professes a love for it. He is highly skeptical about the viability of butanol using the gasification and syngas route, that’s all!


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